Nick Dunlap will go into the 2025 American Express as the defending champion. Although he has a whopping $1,584,00 winner's share on the line this week, his eyes are set on the Ryder Cup in September.This is a big season for all the golfers on the circuit as the Ryder Cup will take place this year. Every player would be vying to make the team and represent their country or continent at the Bethpage Black.Nick Dunlap was recently asked on the NBC Golf Today show, how much the Ryder Cup was on his mind. The US golfer turned pro early last year after his American Express victory. Although the host acknowledged that the question "doesn't get asked much" to golfers who have been pros for little over a year, the 21-year-old player claimed that the biennial tournament was certainly one of his aims this year."Yeah, I would probably say number one. Something I have always thought would be an absolute experiene and a dream come true for me. And to represent your country is way more than just playing for yourself every week so I always watched it as a kid growing up. To be there, at Bethpage, wearing red, white and blue would be awesome," he said.Nick Dunlap was the first amateur to win a PGA Tour event in 33 years. He will want to emulate a similar success story this year.Who is paired along with Nick Dunlap at the 2025 American Express Round 1?Nick Dunlap and Sam Burns (Source: Getty)Nick Dunlap will tee off with Sam Burns at the La Quinta Course in the first round of the 2025 American Express. The duo will start at 8:41 am PST. They are a part of the first tee on the course.Here's looking at the full tee times and pairings for Round 1 of the 2025 American Express (please note all times are in PST):La Quinta Country Club1st tee8:30 am: Max Greyserman, Kevin Streelman8:41 am: Nick Dunlap, Sam Burns8:52 am: John Pak, Tim Widing9:03 am: Adam Hadwin, Ryan Palmer9:14 am: Patrick Cantlay, Billy Horschel9:25 am: Matteo Manassero, Michael Thorbjornsen9:36 am: Charley Hoffman, Eric Cole9:47 am: Keith Mitchell, Brandt Snedeker9:58 am: Justin Thomas, Jason Day10:09 am: Greyson Sigg, Vince Whaley10:20 am: Camilo Villegas, Nico Echavarria10:31 am: Wyndham Clark, Rickie Fowler10:42 am: Blades Brown, Isaiah Salinda10th tee8:30 am: Patrick Fishburn, Andrew Novak8:41 am: Tony Finau, Will Zalatoris8:52 am: Aldrich Potgieter, Braden Thornberry9:03 am: Justin Lower, Ben Kohles9:14 am: Chris Kirk, Davis Thompson9:25 am: Rikuya Hoshino, Taylor Dickson9:36 am: Doug Ghim, Sam Ryder9:47 am: Zach Johnson, Kevin Kisner9:58 am: Si Woo Kim, Kurt Kitayama10:09 am: Quade Cummins, Noah Goodwin10:20 am: J.J. Spaun, Rico Hoey10:31 am: Rafael Campos, Peter Malnati10:42 am: Kaito Onishi, Jeremy PaulNicklaus Tournament Course1st tee8:30 am: Ryo Hisatsune, Matti Schmid8:41 am: Chris Gotterup, Adam Svensson8:52 am: Max McGreevy, Hayden Buckley9:03 am: Ben Martin, Chandler Phillips9:14 am: Brice Garnett, Harry Hall9:25 am: Danny Walker, Matthew Riedel9:36 am: Nate Lashley, David Skinns9:47 am: Frankie Capan III, Antoine Rozner9:58 am: Chad Ramey, K.H. Lee10:09 am: Chesson Hadley, Harry Higgs10:20 am: Michael Kim, Mac Meissner10:31 am: Taylor Moore, Lee Hodges10:42 am: Norman Xiong, Brian Campbell10th tee8:30 am: Joel Dahmen, Ben Griffin8:41 am: Brian Harman, Sepp Straka8:52 am: William Mouw, Ryan Gerard9:03 am: Jason Dufner, David Lipsky9:14 am: Mark Hubbard, Daniel Berger9:25 am: Steven Fisk, Trevor Cone9:36 am: Sami Valimaki, Henrik Norlander9:47 am: Danny Willett, Victor Perez9:58 am: Jake Knapp, J.T. Poston10:09 am: Beau Hossler, Will Gordon10:20 am: Tom Hoge, Cameron Young10:31 am: Francesco Molinari, Jhonattan Vegas10:42 am: Alejandro Tosti, Cristobal Del SolarPete Dye Stadium Course1st tee8:30 am: Lanto Griffin, Bud Cauley8:41 am: Luke List, Kevin Yu8:52 am: Kevin Roy, Ricky Castillo9:03 am: Taylor Montgomery, Bronson Burgoon9:14 am: Matt Kuchar, Cam Davis9:25 am: Paul Peterson, Takumi Kanaya9:36 am: Chez Reavie, Aaron Baddeley9:47 am: Nick Taylor, Tom Kim9:58 am: Sungjae Im, Mackenzie Hughes10:09 am: Alex Smalley, Patrick Rodgers10:20 am: Christiaan Bezuidenhout, Harris English10:31 am: Lucas Glover, Erik van Rooyen10:42 am: Kevin Velo, Jackson Suber10th tee8:30 am: Jacob Bridgeman, Joe Highsmith8:41 am: Emiliano Grillo, Adam Schenk8:52 am: Thomas Rosenmueller, Mason Andersen9:03 am: Bill Haas, Andrew Putnam9:14 am: Brendon Todd, Patton Kizzire9:25 am: Anders Albertson, Philip Knowles9:36 am: Trey Mullinax, Carson Young9:47 am: Chan Kim, Sam Stevens9:58 am: Davis Riley, Nick Hardy10:09 am: Kris Ventura, Jesper Svensson10:20 am: Ben Silverman, Wesley Bryan10:31 am: Matt McCarty, Vincent Norrman10:42 am: Will Chandler, Kyle MendozaNick Dunlap will look to retain his title as he tees off on Thursday this week.