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#4 Luis Garcia
The former Spanish international is at number four on our list. He had scored 10 goals in 24 Champions League appearances.
Luis Garcia played a vital role in Liverpool's 2004-05 Champions League triumph and was Liverpool's top scorer during that campaign. He scored five goals in the Champions League that season including their winner in the semi-final against Chelsea.
He was a part of the UEFA Team of the Year in 2005 and he finished as the Champions League runners-up with Liverpool in the 2006-2007 season.
Injuries hampered his progress at Anfield and he eventually left the club for Atletico Madrid in 2007.
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