#5 Charlotte Flair v Sasha Banks (2016)

For one exciting moment, it looked as though the main event of In Your House I - Diesel v Sycho Sid - would also make this list, but Sid had been in main events before as Sid Justice, so that was the end of that.
We had to fast forward three decades for the next time two main-event debutants featured in the closing match on a PPV.
Did Goldberg ruin Bray Wyatt's career? - Watch Now!
That match involved Charlotte Flair and Sasha Banks -- the first time two women had competed not only inside Hell In A Cell but also last on a WWE PPV -- in Sasha’s hometown of Boston, Massachusetts.
On a memorable night in WWE history, Charlotte regained the Raw Women’s Championship after a gruelling 22-minute battle with her fellow Horsewoman.
One wrong move ended Big E's career - Watch Here!