The Serb will face Thanasi Kokkinakis in the second round after overcoming Kwon Soon-woo in four sets on Monday.
Murray, meanwhile, will face 20th seed John Isner for a place in the third round. This will be the ninth meeting between the two and their first since the final of the 2016 Paris Masters. As of now, Murray leads the head-to-head 8-0.
Women's singles 10th seed Emma Raducanu will play her second-round match against Bad Homburg champion Caroline Garcia. Second seed Anett Kontaveit will look to clinch her spot in the third round by beating Germany's Jule Niemeier.
Fifth seed Maria Sakkari will face Bulgarian Viktoriya Tomova while men's singles ninth seed Cameron Norrie will lock horns with Jaume Munar. The Brit's chances of reaching the quarterfinals have received a major boost with the elimination of Halle champion Hubert Hurkacz.
Other players who will be in action on the day include Berlin champion Ons Jabeur, 2018 winner Angelique Kerber, Casper Ruud, Carlos Alcaraz and Jannik Sinner.
So without any further ado, let us take a look at the schedule for Day 3 of Wimbledon (showcourts only):
(Starts at 1:30 pm local time)
(1) Novak Djokovic vs Thanasi Kokkinakis
Followed by: (10) Emma Raducanu vs Caroline Garcia
Followed by: Andy Murray vs (20) John Isner
(Starts at 1 pm local time)
(2) Anett Kontaveit vs Jule Niemeier
Followed by: (9) Cameron Norrie vs Jaume Munar
Followed by: (5) Maria Sakkari vs Viktoriya Tomova
(For more information regarding the schedule for Day 3 of the grasscourt Major, click here.)
Where to watch Wimbledon 2022?
Here's a look at the full list of channels broadcasting the tournament:
Australia: Channel Nine
France: beIN Sports
Germany: Sky Deutschland & ZDF
India: Star Sports
Italy: Sky Italia & Super Tennis
Japan: NHK & WOWOW
New Zealand: Sky NZ
Serbia: RTS & Sport Klub
Spain: Telefonica & Movistar+
UK: BBC & Eurosport
USA: ESPN & Tennis Channel
For more information regarding the broadcasters for Wimbledon, click here.
Wimbledon 2022 - Match Timings for Day 3
The matches start at 11 am local time on most of the courts. On Centre Court and Court 1, the action will commence at 1:30 pm local time and 1 pm local time respectively.