#5 Edge - No Way Out 2009

Edge was forced into retirement due to a serious injury in 2011. The Rated R Superstar was one of the biggest stars in the company, and he was given the first-ever Money in the Bank contract.
No Way Out 2009 was probably one of the most memorable nights of his career because he competed more than once. He is the only star in history to walk into a pay-per-view with one championship and walk out with another.
Look who just shut down all of Tony Khan's critics! More HERE.
Edge walked into the Elimination Chamber match with the WWE Championship but was eliminated from the match by Jeff Hardy after just three minutes. Edge then decided to compete in the other Elimination Chamber match for the World Heavyweight title, taking out Kofi Kingston and stealing his spot.
He eliminated John Cena and Rey Mysterio to became WWE World Heavyweight Champion, walking out of Washington with a different championship.
#4 Chris Jericho - Vengeance 2001

Chris Jericho is one of the poster boys for All Elite Wrestling. Despite this change, Jericho will always be remembered as the man who defeated both The Rock and Stone Cold Steve Austin on the same night to become the Undisputed WWF Champion.
That happened on Vengeance 2001, which was interestingly the last WWF pay-per-view to air on terrestrial TV in the United Kingdom.
The Rock was the World Champion heading into the pay-per-view, but Jericho was able to defeat him in a 20-minute match. He then went on to defeat The Texas Rattlesnake right after in a unification match for the WWF and World Championships.
Jericho officially became the Undisputed World Champion, something he has bragged about for much of his wrestling career since December 9, 2001.