#5. Edge - WWE No Way Out 2009

Before the Elimination Chamber pay-per-view became a thing, it took place at WWE No Way Out. In this case, there were two World title matches. Edge walked into the opening match as the defending WWE Champion and walked out as the World Heavyweight Champion.
Edge was eliminated shockingly early in the chamber match and lost the WWE title (which was eventually won by Triple H). While he wasn't in the main event for the World Heavyweight title, he assaulted Kofi Kingston and took his spot. He proceeded to win the match and pulled off a feat that was never seen before in WWE.
15 shocking wrestling couples - Find out now!
#4. Becky Lynch - Money in the Bank 2019

Becky Lynch was undoubtedly WWE's hottest star post-WrestleMania 35 in 2019. In her first major pay-per-view test, then-double champion Becky Lynch had to put the WWE RAW and SmackDown Women's Championships on the line.
She first retained the RAW Women's title against Lacey Evans, but a post-match attack from her opponent allowed Charlotte Flair to capture the SmackDown Women's Championship. Unfortunately for Flair, her reign would only last minutes, as Bayley cashed in the Money in the Bank briefcase having won it earlier in the night.
Goldberg ruined Bray Wyatt's career? - Watch now!