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Total: 55 (26–29)
| Year | Event | Surface | Winner | Result |
| 2020 | ATP Cup | Outdoor Hard | Novak Djokovic | 6–2, 7–6 |
| 2019 | ATP Masters 1000 Rome | Outdoor Clay | Rafael Nadal | 6-0,4-6,6-1 |
| 2019 | Australian Open | Outdoor Hard | Novak Djokovic | 6-3,6-2,6-3 |
| 2018 | Wimbledon | Outdoor Grass | Novak Djokovic | 6-4,3-6,7-6,3-6,10-8 |
| 2018 | ATP Masters 1000 Rome | Outdoor Clay | Rafael Nadal | 7-6,6-3 |
| 2017 | ATP Masters 1000 Madrid | Outdoor Clay | Rafael Nadal | 6-2,6-4 |
| 2016 | ATP Masters 1000 Rome | Outdoor Clay | Novak Djokovic | 7-5,7-6 |
| 2016 | ATP Masters 1000 Indian Wells | Outdoor Hard | Novak Djokovic | 7-6,6-2 |
| 2016 | Doha | Outdoor Hard | Novak Djokovic | 6-1,6-2 |
| 2015 | ATP Finals | Indoor Hard | Novak Djokovic | 6-3,6-3 |
| 2015 | Beijing | Outdoor Hard | Novak Djokovic | 6-2,6-2 |
| 2015 | Roland Garros | Outdoor Clay | Novak Djokovic | 7-5,6-3,6-1 |
| 2015 | ATP Masters 1000 Monte Carlo | Outdoor Clay | Novak Djokovic | 6-3,6-3 |
| 2014 | Roland Garros | Outdoor Clay | Rafael Nadal | 3-6,7-5,6-2,6-4 |
| 2014 | ATP Masters 1000 Rome | Outdoor Clay | Novak Djokovic | 4-6,6-3,6-3 |
| 2014 | ATP Masters 1000 Miami | Outdoor Hard | Novak Djokovic | 6-3,6-3 |
| 2013 | ATP Finals | Indoor Hard | Novak Djokovic | 6-3,6-4 |
| 2013 | Beijing Open | Outdoor Hard | Novak Djokovic | 6-3,6-4 |
| 2013 | US Open | Outdoor Hard | Rafael Nadal | 6-2,3-6,6-4,6-1 |
| 2013 | ATP Masters 1000 Canada | Outdoor Hard | Rafael Nadal | 6-4,3-6,7-6 |
| 2013 | Roland Garros | Outdoor Clay | Rafael Nadal | 6-4,3-6,6-1,6-7,9-7 |
| 2013 | ATP Masters 1000 Monte Carlo | Outdoor Clay | Novak Djokovic | 6-2,7-6 |
| 2012 | Roland Garros | Outdoor Clay | Rafael Nadal | 6-4,6-3,2-6,7-5 |
| 2012 | ATP Masters 1000 Rome | Outdoor Clay | Rafael Nadal | 7-5,6-3 |
| 2012 | ATP Masters 1000 Monte Carlo | Outdoor Clay | Rafael Nadal | 6-3,6-1 |
| 2012 | Australian Open | Outdoor Hard | Novak Djokovic | 5-7,6-4,6-2,6-7,7-5 |
| 2011 | US Open | Outdoor Hard | Novak Djokovic | 6-2,6-4,6-7,6-1 |
| 2011 | Wimbledon | Outdoor Grass | Novak Djokovic | 6-4,6-1,1-6,6-3 |
| 2011 | ATP Masters 1000 Rome | Outdoor Clay | Novak Djokovic | 6-4,6-4 |
| 2011 | ATP Masters 1000 Madrid | Outdoor Clay | Novak Djokovic | 7-5,6-4 |
| 2011 | ATP Masters 1000 Miami | Outdoor Hard | Novak Djokovic | 4-6,6-3,7-6 |
| 2011 | ATP Masters 1000 Indian Wells | Outdoor Hard | Novak Djokovic | 4-6,6-3,6-2 |
| 2010 | ATP Finals | Indoor Hard | Rafael Nadal | 7-5,6-2 |
| 2010 | US Open | Outdoor Hard | Rafael Nadal | 6-4,5-7,6-4,6-2 |
| 2009 | ATP Finals | Indoor Hard | Novak Djokovic | 7-6,6-3 |
| 2009 | ATP Masters 1000 Paris | Indoor Hard | Novak Djokovic | 6-2,6-3 |
| 2009 | ATP Masters 1000 Cincinnati | Outdoor Hard | Novak Djokovic | 6-1,6-4 |
| 2009 | ATP Masters 1000 Madrid | Outdoor Clay | Rafael Nadal | 3-6,7-6,7-6 |
| 2009 | ATP Masters 1000 Rome | Outdoor Clay | Rafael Nadal | 7-6,6-2 |
| 2009 | ATP Masters 1000 Monte Carlo | Outdoor Clay | Rafael Nadal | 6-3,2-6,6-1 |
| 2009 | ESP vs. SRB WG 1st RD | Outdoor Clay | Rafael Nadal | 6-4,6-4,6-1 |
| 2008 | Beijing Olympics | Outdoor Hard | Rafael Nadal | 6-4,1-6,6-4 |
| 2008 | ATP Masters 1000 Cincinnati | Outdoor Hard | Novak Djokovic | 6-1,7-5 |
| 2008 | London / Queen's Club | Outdoor Grass | Rafael Nadal | 7-6,7-5 |
| 2008 | Roland Garros | Outdoor Clay | Rafael Nadal | 6-4,6-2,7-6 |
| 2008 | ATP Masters 1000 Hamburg | Outdoor Clay | Rafael Nadal | 7-5,2-6,6-2 |
| 2008 | ATP Masters 1000 Indian Wells | Outdoor Hard | Novak Djokovic | 6-3,6-2 |
| 2007 | Tennis Masters Cup | Indoor Hard | Rafael Nadal | 6-4,6-4 |
| 2007 | ATP Masters 1000 Canada | Outdoor Hard | Novak Djokovic | 7-5,6-3 |
| 2007 | Wimbledon | Outdoor Grass | Rafael Nadal | 3-6,6-1,4-1 |
| 2007 | Roland Garros | Outdoor Clay | Rafael Nadal | 7-5,6-4,6-2 |
| 2007 | ATP Masters 1000 Rome | Outdoor Clay | Rafael Nadal | 6-2,6-3 |
| 2007 | ATP Masters 1000 Miami | Outdoor Hard | Novak Djokovic | 6-3,6-4 |
| 2007 | ATP Masters 1000 Indian Wells | Outdoor Hard | Rafael Nadal | 6-2,7-5 |
| 2006 | Roland Garros | Outdoor Clay | Rafael Nadal | 6-4,6-4 |
Total: 2(2–0)
| Year | Tournament | Surface | Winner | Score | Opponents |
| 2009 | Canadian Open | Hard | Nadal/Roig | 7–5, 6–4 | Djokovic/Vemić |
| 2015 | Qatar Open | Hard | Nadal/Mónaco | 7–6(7–3), 6–1 | Djokovic/Krajinović |
Total: 1(0–1)
| Year | Tournament | Surface | Pair | Score | Winner |
| 2010 | Canadian Open | Hard | Djokovic/Nadal | 7–5, 3–6, [8–10] | Pospisil/Raonic |
