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| Year | Player 1 | Country | Player 2 | Country |
| 1968 | Rosemary Casals | USA | Billie Jean King | USA |
| 1969 | Margaret Court | Australia | Judy Tegart | Australia |
| 1970 | Rosemary Casals | USA | Billie Jean King | USA |
| 1971 | Rosemary Casals | USA | Billie Jean King | USA |
| 1972 | Billie Jean King | USA | Betty Stove | Netherlands |
| 1973 | Rosemary Casals | USA | Billie Jean King | USA |
| 1974 | Evonne Goolagong | Australia | Peggy Michel | USA |
| 1975 | Ann Kiyomura | USA | Kazuko Sawamatsu | Japan |
| 1976 | Chris Evert | USA | Martina Navratilova | Czechoslovakia |
| 1977 | Helen Gourlay | Australia | JoAnne Russell | USA |
| 1978 | Kerry Reid | Australia | Wendy Turnbull | Australia |
| 1979 | Billie Jean King | USA | Martina Navratilova | USA |
| 1980 | Kathy Jordan | USA | Anne Smith | USA |
| 1981 | Martina Navratilova | USA | Pam Shriver | USA |
| 1982 | Martina Navratilova | USA | Pam Shriver | USA |
| 1983 | Martina Navratilova | USA | Pam Shriver | USA |
| 1984 | Martina Navratilova | USA | Pam Shriver | USA |
| 1985 | Kathy Jordan | USA | Elizabeth Smylie | Australia |
| 1986 | Martina Navratilova | USA | Pam Shriver | USA |
| 1987 | Claudia Kohde-Kilsch | West Germany | Helena Sukova | Czechoslovakia |
| 1988 | Steffi Graf | West Germany | Gabriela Sabatini | Argentina |
| 1989 | Jana Novotná | Czechoslovakia | Helena Suková | Czechoslovakia |
| 1990 | Jana Novotná | Czechoslovakia | Helena Suková | Czechoslovakia |
| 1991 | Larisa Savchenko Neiland | Soviet Union | Natalia Zvereva | Soviet Union |
| 1992 | Gigi Fernández | USA | Natasha Zvereva | Belarus |
| 1993 | Gigi Fernández | USA | Natasha Zvereva | Belarus |
| 1994 | Gigi Fernández | USA | Natasha Zvereva | Belarus |
| 1995 | Jana Novotna | Czechoslovakia | Arantxa Sanchez Vicario | Spain |
| 1996 | Martina Hingis | Switzerland | Helena Sukova | Czechoslovakia |
| 1997 | Gigi Fernandez | USA | Natasha Zvereva | Belarus |
| 1998 | Martina Hingis | Switzerland | Jana Novotna | Czechoslovakia |
| 1999 | Lindsay Davenport | USA | Corina Morariu | USA |
| 2000 | Serena Williams | USA | Venus Williams | USA |
| 2001 | Lisa dRaymon | USA | Rennae Stubbs | Australia |
| 2002 | Serena Williams | USA | Venus Williams | USA |
| 2003 | Kim Clijsters | Belgium | Ai Sugiyama | Japan |
| 2004 | Cara Black | Zimbabwe | Rennae Stubbs | Australia |
| 2005 | Cara Black | Zimbabwe | Liezel Huber | South Africa |
| 2006 | Yan Zi | China | Zheng Jie | China |
| 2007 | Cara Black | Zimbabwe | Liezel Huber | South Africa |
| 2008 | Serena Williams | USA | Venus Williams | USA |
| 2009 | Serena Williams | USA | Venus Williams | USA |
| 2010 | Vania King | USA | Yaroslava Shvedova | Kazakhstan |
| 2011 | Kveta Peschke | Czechoslovakia | Katarina Srebotnik | Slovenia |
| 2012 | Serena Williams | USA | Venus Williams | USA |
| 2013 | Hsieh Su Wei | Chinese Taipei | Peng Shuai | China |
| 2014 | Sara Errani | Italy | Roberta Vinci | Italy |
| 2015 | Martina Hingis | Switzerland | Sania Mirza | India |
| 2016 | Serena Williams | USA | Venus Williams | USA |
| 2017 | Ekaterina Makarova | Russia | Elena Vesnina | Russia |
| 2018 | Barbora Krejcikova | Czechoslovakia | Katerina Siniakova | Czechoslovakia |
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